Pretty sure it's not in the standard code.
You can modify the modules/Roster.php and add the following:
        function memberslistmain()
        {
                $blob = "";
                $count = 0;
                $result = $this -> bot -> db -> select("SELECT nickname, last_seen FROM #___users LEFT JOIN alts ON #___users.nickname = alts.alt WHERE user_level = " . MEMBER . " AND alts.alt IS NULL ORDER BY nickname ASC");
                if (!empty($result))
                {
                        $inside = "##blob_title##:::: <botname>'s Mains List ::::##end##\n\n";
                        foreach ($result as $val)
                        {
                                $count++;
                                $inside .= "##blob_text##• " . $val[0];
                                if ($val[1] > 0)
                                {
                                        $inside .= ", last seen at " . gmdate($this -> bot -> core("settings") -> get("Time", "FormatString"), $val[1]);
                                }
                                else
                                {
                                        $inside .= ", never seen online";
                                }
                                $inside .= "##end## ".$this -> bot -> core("tools") -> chatcmd("whois " . $val[0], "[Whois]")."\n";
                        }
                        $blob = " :: " . $this -> bot -> core("tools") -> make_blob("click to view", $inside);
                }
                return $count . " mains in <botname>" . $blob;
        }
You'd also have to change the command_handler code to allow for a !member main command.